Photocatalytic Oxidation of Chlorantraniliprole, Imidacloprid, Pirimicarb, Thiamethoxam and Their Main Photoreaction InterMediates as Impacted by Water Matrix Composition under UVA-LED Exposure

نویسندگان

چکیده

Processes on wastewater treatment plants (WWTP) are not always efficient for pollutant removal. A new, low-cost, and effective technology is needed. In this work, the photocatalytic degradation of four insecticides, chlorantraniliprole, imidacloprid, pirimicarb, thiamethoxam, has been examined in different water matrices (irrigation water, leaching waters, WWTP effluent). Lab experiments were conducted with TiO2 ZnO, as photocatalysts, without Na2S2O8 an oxidant, exposed to UVA irradiation LED lamps. Previously, loadings ZnO assessed disappearance kinetics insecticides know optimal efficiency. The effect matrices, susceptible being contaminated target was discussed when system TiO2/Na2S2O8 applied. abatement their main transformation products (TPs) also monitored during studied photoperiods. total 13 TPs detected studied. All them formed eliminated photoperiod, except thiamethoxam urea which present from beginning due its hydrolysis water. conclusion, UVA-LED lamps a good source carry out heterogeneous photocatalysis WWTP, since high efficiency, long lifetime, effectiveness

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ژورنال

عنوان ژورنال: Catalysts

سال: 2021

ISSN: ['2073-4344']

DOI: https://doi.org/10.3390/catal11050609